物理有機化学
(Physical Organic Chemistry から転送)
出典: フリー百科事典『ウィキペディア（Wikipedia）』 (2024/05/30 07:45 UTC 版)
物理有機化学（ぶつりゆうきかがく、英: physical organic chemistry）とは、化学構造と反応性の関係に注目する有機化学の一分野である。主に物理化学の実験的手法を有機分子の研究に応用することによってそれらの関係を分析する。具体的には、有機反応の反応速度論、出発物質の相対的な化学的安定性、反応中間体、遷移状態、 化学反応の生成物、化学的反応に影響を与える溶媒和および分子間相互作用の非共有結合的な様相などが挙げられる。このような研究でもたらされた理論的・実験的フレームワークにより、各有機反応において溶液中または固体状態での構造変化が反応機構や反応速度に与える影響の理解につながる。
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