遷移状態理論
出典: フリー百科事典『ウィキペディア(Wikipedia)』 (2022/10/31 09:29 UTC 版)
遷移状態理論(せんいじょうたいりろん、英: Transition state theory、略称: TST)は、素化学反応の反応速度を説明する。本理論は反応物と活性化した遷移状態複合体との間の特別な種類の化学平衡(擬平衡、準平衡)を仮定する[1]。
- ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). オンライン版: (2006-) "transition state theory".
- ^ Truhlar, D. G.; Garrett, B. C.; Klippenstein, S. J. (1996). “Current Status of Transition-State Theory”. J. Phys. Chem. 100 (31): 12771–12800. doi:10.1021/jp953748q.
- ^ Laidler, K.; King, C. (1983). “Development of transition-state theory”. J. Phys. Chem. 87 (15): 2657. doi:10.1021/j100238a002.
- ^ Laidler, K.; King, C. (1998). “A lifetime of transition-state theory”. The Chemical Intelligencer 4 (3): 39.
- ^ a b Laidler, K. J. (1969). Theories of Chemical Reaction Rates. McGraw-Hill
- ^ Anslyn, E. V.; Dougherty, D. A. (2006). “Transition State Theory and Related Topics”. Modern Physical Organic Chemistry. University Science Books. pp. 365–373. ISBN 1891389319
- ^ Herzfeld, K. E. (1919). “Zur Theorie der Reaktionsgeschwindigkeiten in Gasen”. Annalen der Physik 364 (15): 635–667. Bibcode: 1919AnP...364..635H. doi:10.1002/andp.19193641504 .
- ^ Keith J. Laidler, Chemical Kinetics (3rd ed., Harper & Row 1987), p.88 ISBN 0-06-043862-2
- ^ Luo, G.; Kuech, T. F.; Morgan, D. (2018). “Transition state redox during dynamical processes in semiconductors and insulators”. NPG Asia Materials 10 (4): 45–51. arXiv:1712.01686. Bibcode: 2018npjAM..10...45L. doi:10.1038/s41427-018-0010-0.
- ^ 統計力学の入門的取扱いとアイリングの式の初歩的導出については以下の文献を見よ: Lowry and Richardson, Mechanism and Theory in Organic Chemistry, 3rd ed. (Harper & Row, 1987), pp. 248-253.
- ^ Steinfeld, Jeffrey L.; Francisco, Joseph S.; Hase, William L. (1999). Chemical Kinetics and Dynamics (2nd ed.). Prentice-Hall. pp. 289-293. ISBN 0-13-737123-3
- ^ Laidler, Keith J. (1981). “Symbolism and terminology in chemical kinetics”. Pure and Applied Chemistry (IUPAC) 53: 753-771 2019年8月9日閲覧. "See p.765, note m."
- ^ Steinfeld, Jeffrey L.; Francisco, Joseph S.; Hase, William L. (1999). Chemical Kinetics and Dynamics (2nd ed.). Prentice-Hall. p. 302. ISBN 0-13-737123-3
- ^ Carpenter, Barry K. (1984). Determination of organic reaction mechanisms. New York: Wiley. ISBN 0471893692. OCLC 9894996
- ^ Lowry, Thomas H. (1987). Mechanism and theory in organic chemistry. Richardson, Kathleen Schueller. (3rd ed.). New York: Harper & Row. ISBN 0060440848. OCLC 14214254
- ^ Eliel, Ernest L. (Ernest Ludwig) (1994). Stereochemistry of organic compounds. Wilen, Samuel H., Mander, Lewis N.. New York: Wiley. ISBN 0471016705. OCLC 27642721
- ^ Eyring, H. (1935). “The Activated Complex in Chemical Reactions”. J. Chem. Phys. 3 (2): 107–115. Bibcode: 1935JChPh...3..107E. doi:10.1063/1.1749604.
- ^ Masel, R. (1996). Principles of Adsorption and Reactions on Solid Surfaces. New York: Wiley
- ^ Pineda, J. R.; Schwartz, S. D. (2006). “Protein dynamics and catalysis: The problems of transition state theory and the subtlety of dynamic control”. Phil. Trans. R. Soc. B 361 (1472): 1433–1438. doi:10.1098/rstb.2006.1877. PMC 1647311. PMID 16873129 .
- ^ Truhlar, D.; Garrett, B. (1984). “Variational Transition State Theory”. Annu. Rev. Phys. Chem. 35: 159–189. Bibcode: 1984ARPC...35..159T. doi:10.1146/annurev.pc.35.100184.001111 .
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