ケック不斉アリル化
出典: フリー百科事典『ウィキペディア（Wikipedia）』 (2018/02/21 01:34 UTC 版)
有機化学において、ケック不斉アリル化（ケックふせいアリルか、英: Keck asymmetric allylation）は、アルデヒドへのアリル基の求核付加を含む化学反応である。触媒はチタンをルイス酸として含むキラル錯体である。触媒のキラリティーが立体選択的付加を誘導するため、生成物の2級アルコールは触媒の選択に基づいて予測可能な絶対配置を持つ。この人名反応はゲイリー・ケックに由来する。
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[続きの解説]
「ケック不斉アリル化」の続きの解説一覧
- 1 ケック不斉アリル化とは
- 2 ケック不斉アリル化の概要
- ケック不斉アリル化のページへのリンク
