ベント則
(Bent's rule から転送)
出典: フリー百科事典『ウィキペディア（Wikipedia）』 (2020/03/26 23:44 UTC 版)
ベント則（ベントそく、英語: Bent's rule）は、分子内の中心原子の混成軌道と置換基の電気陰性度との関係を表す規則である[1][2]。 ヘンリー・ベントはこの規則について次のように記述している[2][3]。
- ^ a b c Weinhold, F.; Landis, C. L. (2005), Valency and Bonding: A Natural Donor-Acceptor Perspective (1st ed.), Cambridge: Cambridge University Press, ISBN 978-0-521-83128-4
- ^ a b c d e f g Bent, H. A. (1961), “An appraisal of valence-bond structures and hybridization in compounds of the first-row elements”, Chem. Rev. 61 (3): 275–311, doi:10.1021/cr60211a005
- ^ 俣野 善博, 近藤 和弘, 村上 泰興, 河内 敦「十字路」『有機合成化学協会誌』第59巻第9号、2001年、 904頁、 doi:10.5059/yukigoseikyokaishi.59.904。
- ^ Foster, J. P.; Weinhold, F. (1980), “Natural hybrid orbitals”, J. Am. Chem. Soc. 102 (24): 7211–7218, doi:10.1021/ja00544a007
- ^ Alabugin, I. V.; Bresch S.; Gomes, G. P. (2015). “Orbital Hybridization: a Key Electronic Factor in Control of Structure and Reactivity”. J. Phys. Org. Chem. 28: 147–162. doi:10.1002/poc.3382.
- ^ Alabugin, I. V.; Bresch S.; Manoharan, M. (2014). “Hybridization Trends for Main Group Elements and Expanding the Bent’s Rule Beyond Carbon: More than Electronegativity”. J. Phys. Chem. A 118: 3663– 3677. doi:10.1021/jp502472u.
- ^ a b Pauling, L. (1931), “The nature of the chemical bond. Application of results obtained from the quantum mechanics and from a theory of paramagnetic susceptibility to the structure of molecules”, J. Am. Chem. Soc. 53 (4): 1367–1400, doi:10.1021/ja01355a027
- ^ Slater, J. C. (1931), “Directed Valence in Polyatomic Molecules”, Phys. Rev. 37 (5): 481–489, Bibcode: 1931PhRv...37..481S, doi:10.1103/PhysRev.37.481
- ^ Coulson, C. A. (1961), Valence (2nd ed.), Oxford: Clarendon Press
- ^ a b c Walsh, A. D. (1947), “The properties of bonds involving carbon”, Discuss. Faraday Soc. 2: 18–25, doi:10.1039/DF9470200018
- ^ Muller, N.; Pritchard, D. E. (1959), “C13 in Proton Magnetic Resonance Spectra. I. Hydrocarbons”, J. Chem. Phys. 31 (3): 768–771, Bibcode: 1959JChPh..31..768M, doi:10.1063/1.1730460
- ^ Muller, N.; Pritchard, D. E. (1959), “C13 in Proton Magnetic Resonance Spectra. II. Bonding in Substituted Methanes”, J. Chem. Phys. 31 (6): 1471–1476, Bibcode: 1959JChPh..31.1471M, doi:10.1063/1.1730638
- ^ Bent, H. A. (1960), “Distribution of atomic s character in molecules and its chemical implications”, J. Chem. Educ. 37 (12): 616–624, Bibcode: 1960JChEd..37..616B, doi:10.1021/ed037p616
- ^ Taft Jr., R. W. (1957), “Concerning the Electron—Withdrawing Power and Electronegativity of Groups”, J. Chem. Phys. 26 (1): 93–96, Bibcode: 1957JChPh..26...93T, doi:10.1063/1.1743270
- ^ a b c Coulson, C. A. (1961), Valence (2nd ed.), Oxford: Clarendon Press, pp. 203–5 Non–equivalent hybrids
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