トリヒドリドアルミニウム
水素化アルミニウム
(Aluminum hydride から転送)
出典: フリー百科事典『ウィキペディア(Wikipedia)』 (2024/01/05 03:37 UTC 版)
水素化アルミニウム(すいそかアルミニウム、aluminum hydride)またはアラン(alane)は、無色の固体で化学式がAlH3で表される無機化合物である。極めて酸化されやすく空気中で自然発火するため危険物第3類に分類されている。そのため研究室内で還元剤として有機合成に使われる[1]以外ほとんど見られない。
- ^ Brown, H. C.; Krishnamurthy, S. Tetrahedron 1979, 35, 567.
- ^ a b Lund, Gary K., Hanks, Jami M., Johnston, Harold E., US Patent and Trade Office, 2007, Pat. Application # 20070066839
- ^ Turley J W,. Rinn H W (1969). “The crystal structure of aluminum hydride”. Inorganic Chemistry 8 (1): 18-22. doi:10.1021/ic50071a005.
- ^ F. A. Kurth, R. A. Eberlein, Schnöckel H.-G., A. J. Downs, C. R. Pulham, (1993). “Molecular aluminium trihydride, AlH3: generation in a solid noble gas matrix and characterisation by its infrared spectrum and Ab initio calculations”. J. Chem. Soc., Chem. Communications (16): 1302. doi:10.1039/C39930001302.
- ^ Andrews, Lester; Wang, Xuefeng (2003). “The Infrared Spectrum of Al2H6 in Solid Hydrogen”. Science 299 (5615): 2049-2052. doi:10.1126/science.1082456. PMID 12663923.
- ^ Pulham C.R., Downs A.J., Goode M.J, Rankin D.W.H. Roberson H.E. (1991). “Gallane: Synthesis, Physical and Chemical Properties, and Structure of the Gaseous Molecule Ga2H6 As Determined by Electron Diffraction”. Journal of the American Chemical Society 113 (14): 5149-5162. doi:10.1021/ja00014a003.
- ^ F. M. Brower, N. E. Matzek, P. F. Reigler, H. W. Rinn, C. B. Roberts, D. L. Schmidt, J. A. Snover, K. Terada (1976). “Preparation and properties of aluminum hydride”. Journal of the American Chemical Society (J. Am. Chem. Soc.) 98 (9): 2450-2454. doi:10.1021/ja00425a011.
- ^ A. E. Finholt, A. C. Bond, Jr., H. I. Schlesinger (1947). “Lithium Aluminum Hydride, Aluminum Hydride and Lithium Gallium Hydride, and Some of their Applications in Organic and Inorganic Chemistry”. J. Am. Chem. Soc. 69 (5): 1199-1203. doi:10.1021/ja01197a061.
- ^ U.S. Pat. No. 6228338.
- ^ D. L. Schmidt, C. B. Roberts, P. F. Reigler "Aluminum Trihydride-diethyl etherate: (Etherated Alane)" Inorganic Syntheses, 1973, Volume 14, p. 47-52. doi:10.1002/9780470132456.ch10
- ^ N.M. Alpatova, T.N. Dymova, Yu.M. Kessler, and O.R. Osipov, Russ. Chem. Rev., 37, 99-114 (1968); K.N. Semenenko, B.M. Bulychev, and E.A Shevlyagina, Russ. Chem. Rev., 35, 649-658 (1966); O.R. Osipov, N.M. Alpatova, and Yu.M. Kessler, Elektrokhimiya, 2, 984 (1966)
- ^ H. Clasen, German Patent, 1141623, 1962
- ^ “Aluminum Hydride”. 2020年4月9日閲覧。
- ^ Klebanoff, Lennie (2016-04-21) (英語). Hydrogen Storage Technology: Materials and Applications. Taylor & Francis. ISBN 978-1-4398-4108-2
- ^ Alpatova, N. M.; Dymova, T. N.; Kessler, Yu. M.; Osipov, O. R. (1968). “Physicochemical Properties and Structure of Complex Compounds of Aluminium Hydride”. Russian Chemical Reviews 37 (2): 99-114. Bibcode: 1968RuCRv..37...99A. doi:10.1070/RC1968v037n02ABEH001617.
- ^ Semenenko, K. N.; Bulychev, B. M.; Shevlyagina, E. A. (1966). “Aluminium Hydride”. Russian Chemical Reviews 35 (9): 649-658. Bibcode: 1966RuCRv..35..649S. doi:10.1070/RC1966v035n09ABEH001513.
- ^ Osipov, O. R.; Alpatova, N. M.; Kessler, Yu. M. (1966). “none”. Elektrokhimiya 2: 984.
- ^ Zidan, R.; Garcia-Diaz, B. L.; Fewox, C. S.; Stowe, A. C.; Gray, J. R.; Harter, A. G. (2009). “Aluminium hydride: a reversible material for hydrogen storage”. Chemical Communications (25): 3717-3719. doi:10.1039/B901878F. PMID 19557259 .
- ^ Martinez-Rodriguez, M. J.; Garcia-Diaz, B. L.; Teprovich, J. A.; Knight, D. A.; Zidan, R. (2012). “Advances in the electrochemical regeneration of aluminum hydride”. Applied Physics A: Materials Science & Processing 106 (25): 545-550. Bibcode: 2012ApPhA.106..545M. doi:10.1007/s00339-011-6647-y.
- ^ DE patent 1141623, Clasen, H., "Verfahren zur Herstellung von Aluminiumhydrid bzw. aluminiumwasserstoffreicher komplexer Hydride", issued 1962-12-27, assigned to Metallgesellschaft
- ^ US patent 8470156, Zidan, R., "Electrochemical process and production of novel complex hydrides", issued 2013-06-25, assigned to Savannah River Nuclear Solutions, LLC
- ^ Saitoh, H; Sakurai, Y; Machida, A; Katayama, Y; Aoki, K (2010). “In situX-ray diffraction measurement of the hydrogenation and dehydrogenation of aluminum and characterization of the recovered AlH3”. Journal of Physics: Conference Series 215 (1): 012127. Bibcode: 2010JPhCS.215a2127S. doi:10.1088/1742-6596/215/1/012127. ISSN 1742-6596.
- ^ a b グリーンウッド, ノーマン; アーンショウ, アラン (1997). Chemistry of the Elements (英語) (2nd ed.). バターワース=ハイネマン. ISBN 978-0-08-037941-8。
- ^ Atwood JL , Bennett FR, Elms FM, Jones C, Raston CL, Robinson KD (1991). “Tertiary amine stabilized dialane”. J. Am. Chem. Soc. 113 (21): 8183-8185. doi:10.1021/ja00021a063.
- ^ Jong-Ho Yun, Byoung-Youp Kim and Shi-Woo Rhee (1998). “Metal-organic chemical vapor deposition of aluminum from dimethylethylamine alane”. Thin Solid Films 312 (1-2): 259-263. doi:10.1016/S0040-6090(97)00333-7.
- ^ Galatsis, P. In Encyclopedia of Reagents for Organic Synthesis
- ^ Ayres, D. C.; Sawdaye, R. J. Chem. Soc., Perkin Trans, 1967, 581.
- ^ E. J. Corey, David E. Cane (1971). “Controlled hydroxymethylation of ketones”. J. Org. Chem. 36 (20): 3070-3070. doi:10.1021/jo00819a047.
- ^ Danishefsky, S.; Regan, J. Tetrahedron, 1962, 559.
- ^ S. Takano, M. Akiyama, S. Sato, K. Orgasawara, Chem. Lett., 1983, 1593.
- ^ W. J. Richter (1981). “Asymmetric synthesis at prochiral centers: substituted 1, 3-dioxolanes”. J. Org. Chem. 46 (25): 5119-5124. doi:10.1021/jo00338a011.
- ^ K. Maruoka, S. Saito, T. Ooi, H. Yamamoto, H. Synlett, 1991, 255.
- ^ A. Claesson, L.-I. Olsson (1979). “Allenes and acetylenes. 22. Mechanistic aspects of the allene-forming reductions (SN2' reaction) of chiral propargylic derivatives with hydride reagents”. J. Am. Chem. Soc. 101 (24): 7302-7311. doi:10.1021/ja00518a028.
- ^ Calabro, M. (2011). “Overview of Hybrid Propulsion”. Progress in Propulsion Physics 2: 353-374. Bibcode: 2011EUCAS...2..353C. doi:10.1051/eucass/201102353. ISBN 978-2-7598-0673-7 .
- ^ 池田一貴, 大友季哉, 武藤俊介, 折茂慎一「アルミニウム水素化物の合成および原子配置と水素放出特性」『セラミックス』第46巻第3号、日本セラミックス協会、2011年、174-177頁。
- 1 水素化アルミニウムとは
- 2 水素化アルミニウムの概要
- 3 反応
- 4 関連項目
- Aluminum hydrideのページへのリンク